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Ana takes on Australian 16-year-old Ashleigh Barty in the Hopman Cup on Wednesday as Serbia looks to build upon its victory over Italy.
The top seeds are favourites to defeat the home nation, with world No.1 Novak Djokovic coming up against 52-ranked Bernard Tomic in the opening rubber of the tie at 5.45pm local time (10am Central European Time; 4am Eastern Time).
Immediately afterwards, Ana will face Barty, the world No.175. The tie will end with a mixed doubles rubber.