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Ana will take on world No.121 Marta Sirotkina of Russia in the first round of the Monterrey Open, which begins in Monday. Ana's match is expected to take place on Tuesday.
Should she overcome the 22-year-old, who will be appearing in only her second WTA main draw, Ana will take on either defending champion Timea Babos or Mexican wild card Ana Sofia Sanchez.
Sixth seed Yanina Wickmayer of Belgium could await in the quarter-finals, while second seed Marion Bartoli is a potential semi-final opponent.
The seeded players in the top half of the draw, whom Ana cannot face until the final, are No.1 Angelique Kerber, No.3 Maria Kirilenko, No.7 Ursula Radwanska and No.8 Ayumi Morita.